Valorisation of N and P from waste water by using natural reactive hybrid sorbents: Nutrients (N,P,K) release evaluation in amended soils by dynamic experiments.

The removal of nutrients (nitrogen (N), phosphorous (P)) from waste water has become a resource recovery option in recent regulations worldwide, as observed in the European Union. Although both of these nutrients could be recovered from the sludge line, >70-75% of the N and P is discharged into the water line. Efforts to improve the nutrient recovery ratios have focused on developing low-cost technologies that use sorption processes. In this study, a natural zeolite (clinoptilolite type) in its potassium (K) form was impregnated with hydrated metal oxides and used to prepare natural hybrid reactive sorbents (HRS) for the simultaneous recovery of ammonium (NH4+) and phosphate (PO43-) from treated urban waste water. Three unfertile soils (e.g., one acidic and two basic) amended with N-P-K charged HRS were leached with deionized water (e.g. to simulate infiltration in the field) at two- and three-day time intervals over 15 different leaching cycles (equivalent to 15 bed volumes). The N-P-K leaching profiles for the three charged hybrid sorbents exhibited continuous nutrient release, with their values dependent on the composition of minerals in the soils. In the basic soil that is rich in illite and calcite, the release of potassium (K+) and ammonium (NH4+) is favoured by-ion exchange with calcium (Ca2+) and accordingly diminishes the release of phosphate (PO43-) due to its limited solubility in saturated calcite solutions (pH8 to 9). The opposite is true for sandy soils that are rich in albite (both acidic and basic), whereas the release of NH4+ and K+ was limited and the values of both ions measured in the leaching solutions were below 1mg/L. Their leaching solutions were poor in Ca2+, and the release of PO43- was higher (up to 12mgP-PO43-/L). The nutrient releases necessary for plant growth were provided continuously and were controlled primarily by the soil mineral dissolution rates fixing the soil aqueous solution composition (e.g. pH and ionic composition; in particular, the presence of calcite is a determinant for nutrient release, especially in alkaline soils). The N-P-K charged HRS sorbents that were used for soil amendment may be an alternative for avoiding nutrient leaching and reaching the goals of soil sustainability in agriculture and reducing the nutrient overloading of surface waters.